Document Type

Article

Publication Date

3-2011

DOI

10.1063/1.3564

Publication Title

Applied Physics Letters

Volume

98

Issue

101910

Pages

1-3

Abstract

The dielectric function of Ag nanoparticle films, deduced from an analysis of in situ real-time spectroscopic ellipsometry (RTSE) measurements, is found to evolve with time during deposition in close consistency with the film structure, deduced in the same RTSE analysis. In the nucleation regime, the intraband dielectric function component is absent and plasmon polariton behavior dominates. Only at nuclei contact, does the intraband amplitude appear, increasing above zero. Both intraband and plasmon amplitudes coexist during surface smoothening associated with coalescence. The intraband relaxation time increases rapidly after surface smoothening is complete, also in consistency with the thin film structural evolution.

Original Publication Citation

Little, S.A., Collins, R.W., & Marsillac, S. (2011). Analysis of interband, intraband, and plasmon polariton transitions in silver nanoparticle films via in situ real-time spectroscopic ellipsometry. Applied Physics Letters, 98(101910), 1-3. doi: 10.1063/1.3564894

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