Date of Award
Summer 1973
Document Type
Thesis
Degree Name
Master of Science (MS)
Department
Chemistry & Biochemistry
Program/Concentration
Chemistry
Committee Director
Roy L. Williams
Committee Member
Robert L. Ake
Committee Member
Billy T. Upchurch
Call Number for Print
Special Collections LD4331.C45J63
Abstract
The copper(II) complexes of the picolinic acid bydrazide (PH), the dipicolinic acid dibydrazide (DPH), and the 2,2'-bisacylbydrazide of 3,3'-bipyridine (DAR) ligand systems have been prepared and have been characterized by infrared spectroscopy. Coordination has been proposed to occur between the terminal amine, the amide nitrogen, and the ring nitrogen in each of the respective complexes.
Evidence for the loss of the amide hydrogen upon complexation of PH, DPH, and DAH with copper(II) has been observed by the n.m.r. study of the zinc(II) complexes of the PH and DAH ligand systems. This is in support of the structures proposed above for the copper(II) complexes.
Rights
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DOI
10.25777/6v31-rd21
Recommended Citation
Johnson, William L..
"Complexes of the 2,2'-Bisacylhydrazide of 3,3'-Bipyridine and the Dipicolinic Acid Dihydrazide Ligand Systems"
(1973). Master of Science (MS), Thesis, Chemistry & Biochemistry, Old Dominion University, DOI: 10.25777/6v31-rd21
https://digitalcommons.odu.edu/chemistry_etds/126