Document Type
Article
Publication Date
2013
DOI
10.5194/acp-13-4253-2013
Publication Title
Atmospheric Chemistry and Physics
Volume
13
Issue
8
Pages
4253-4263
Abstract
The lifetimes of CFC-11 and CFC-12 have been evaluated using global observations of their stratospheric distributions from satellite-based instruments over the time period from 1992 to 2010. The chlorofluorocarbon (CFC) datasets are from the Cryogen Limb Array Etalon Spectrometer (CLAES), the Cryogenic Infrared Spectrometers and Telescopes for the Atmosphere (CRISTA-1 and CRISTA-2), the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), and the Atmospheric Chemistry Experiment (ACE). Stratospheric loss rates were calculated using an ultraviolet radiative transfer code with updated cross section and solar irradiance data. Mean steady-state lifetimes based on these observations are 44.7 (36-58) yr for CFC-11 and 106.6 (90-130) yr for CFC-12, which are in good agreement with the most recent WMO ozone assessment. There are two major sources of error in calculating lifetimes using this method. The first important error arises from uncertainties in tropical stratospheric observations, particularly for CFC-11. Another large contribution to the error is due to uncertainties in the penetration of solar ultraviolet radiation at wavelengths between 185 and 220 nm, primarily in the tropical stratosphere between 20 and 35 km altitude.
Original Publication Citation
Minschwaner, K., Hoffmann, L., Brown, A., Riese, M., Muller, R., & Bernath, P. F. (2013). Stratospheric loss and atmospheric lifetimes of CFC-11 and CFC-12 derived from satellite observations. Atmospheric Chemistry and Physics, 13(8), 4253-4263. doi: 10.5194/acp-13-4253-2013
ORCID
0000-0002-1255-396X (Bernath)
Repository Citation
Minschwaner, K.; Hoffmann, L.; Brown, A.; Riese, M.; Müller, R.; and Bernath, P. F., "Stratospheric Loss and Atmospheric Lifetimes of CFC-11 and CFC-12 Derived From Satellite Observations" (2013). Chemistry & Biochemistry Faculty Publications. 34.
https://digitalcommons.odu.edu/chemistry_fac_pubs/34