Document Type
Article
Publication Date
2025
DOI
10.1021/acsomega.5c09607
Publication Title
ACS Omega
Volume
10
Issue
50
Pages
62176-62181
Abstract
The addition of a strong Lewis acid, tris(pentafluorophenyl)borane, facilitates the reduction of Pd(cod)Cl₂ with Et₃SiH to form palladium nanoparticles in organic solvents. It was found that these palladium nanoparticles are capable of selective monoisomerization of linear alkenes. This heterogeneous palladium catalyst is tolerant of a wide variety of functional groups, confirmed by substrate and robustness screenings. It is also possible to utilize poly(methylhydro)siloxane, an industrial waste byproduct, as the reductant to enable similar isomerization chemistry.
Rights
© 2025 The Authors.
This publication is licensed under a Creative Commons Attribution 4.0 International (CC BY 4.0) License.
Original Publication Citation
Miller, P. D., & Bender, T. A. (2025). Formation of pyramidal palladium enhanced by B(C₆F₅)₃ additive enabling selective alkene monoisomerization. ACS Omega, 10(50), 62176-62181. https://doi.org/10.1021/acsomega.5c09607
ORCID
0000-0002-0146-0346 (Miller), 0000-0002-5001-4414 (Bender)
Repository Citation
Miller, Paul D. and Bender, Trandon A., "Formation of Pyramidal Palladium Enhanced by B(C₆F₅)₃ Additive Enabling Selective Alkene Monoisomerization" (2025). Chemistry & Biochemistry Faculty Publications. 382.
https://digitalcommons.odu.edu/chemistry_fac_pubs/382
Supporting Information