Document Type

Article

Publication Date

5-2003

DOI

10.1063/1.1565823

Publication Title

Journal of Applied Physics

Volume

93

Issue

9

Pages

5456-5459

Abstract

The evolution of the band structure of β-In2 S3−3x O3x (BISO) thin films grown by physical vapor deposition, with composition x, is investigated using x-ray photoelectron spectroscopy. It is shown that the energy difference between the valence-band level and the Fermi level remains nearly constant as the optical band gap of the films increases. As a consequence, the difference between the conduction band level and the Fermi level increases as much as the optical band gap of the films. The calculation of the electronic affinity [ ] of the BISO thin films shows that it decreases linearly from 4.65 to 3.85 eV when x varies from 0 to 0.14. This will facilitate fabrication of efficient Cu(InGa)Se2-based solar cells having different absorber layer band gap.

Original Publication Citation

Barreau, N., Marsillac, S., Bernede, J.C., & Assmann, L. (2003). Evolution of the band structure of β-In2 S3−3x O3x buffer layer with its oxygen content. Journal of Applied Physics, 93(9), 5456-5459. doi: 10.1063/1.1565823

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